Coletânea em CD/DVD duplo com os singles em ordem cronológica desde "West And Girls", o cd contem 18 faixas anteriormente lançadas e um novo single "Together". O DVD possuiu 27 Performances para o canal de tv "BBC" e o show completo no "Glastonbury Festival 2010".

Faixas do PSB BBC DVD :

Perfomances de TV da BBC:

1. West End girls (BBC Top Of The Pops)
2. Love comes quickly (BBC Top Of The Pops)
3. Opportunities (Let's make lots of money)
4. Suburbia (BBC Top Of The Pops)
5. It's a sin (BBC Top Of The Pops)
6. Rent (BBC Top Of The Pops)
7. Always on my mind (BBC Top Of The Pops)
8. What have I done to deserve this? (BRITS)
9. Heart (Wogan)
10. Domino dancing (BBC Top Of The Pops)
11. Left to my own devices (BBC Top Of The Pops)
12. So hard (Wogan)
13. Being boring (BBC Top Of The Pops)
14. Can you forgive her? (BBC Top Of The Pops)
15. Liberation (BBC Top Of The Pops)
16. Paninaro '95 (BBC Top Of The Pops)
17. Se a vida é (BBC Top Of The Pops 2)
18. A red letter day (BBC Top Of The Pops)
19. Somewhere (BBC Top Of The Pops)
20. I don't know what you want but I can't give it anymore (BBC Top Of The Pops)
21. New York City boy (BBC Top Of The Pops)
22. You only tell me you love me when you're drunk (BBC Top Of The Pops)
23. Home and dry (BBC Top Of The Pops)
24. I get along (BBC Top Of The Pops 2)
25. Miracles (BBC Top Of The Pops)
26. Flamboyant (BBC Top Of The Pops)
27. I'm with stupid (BBC Top Of The Pops)

Live at Glastonbury 2010:

1. More Than A Dream/Heart
2. Did You Se Me Coming
3. Love Etc.
4. Building A Wall
5. Go West
6. Two Divided By Zero
7. Why Don't We Live Together
8. New York City Boy
9. Always On My Mind
10. Closer To The Heaven/Left To My Own Devices
11. Do I Have To ?
12. King's Cross
13. Jealousy
14. Suburbia
15. What Have I Done To Deserve This?
16. All Over The World
17. Se A Vida É/Discoteca/Domino Dancing
18. Viva La Vida
19. Being Boring
20. West And Girls